676675
Aldrich
(+)-9-(1S, 2S-Pseudoephedrinyl)-(10R)-(trimethylsilyl)-9-borabicyclo[3.3.2]decane
| Synonym: | N,α-Dimethyl-β-[[(10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]dec-9-yl]oxy]-(αS,βS)-benzeneethanamine |
| CAS Number: | 848618-13-3 |
| Linear Formula: | C22H38BNOSi |
| Molecular Weight: | 371.44 |
| MDL number: | MFCD09265094 |
| PubChem Substance ID: | 24885323 |
Description
| Application | Air-stable, crystalline pseudoephedrine borinic acid complex which when treated with an appropriate Grignard reagent provides access to homoallylic or homopropargylic alcohols and α-allenyl carbinols.1,2,3 |
Properties
| optical activity | [α]22/D +60°, c = 4.5 in chloroform-d |
| mp | 130-134 °C |
Safety
| Personal Protective Equipment | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26 |
| WGK Germany | 3 |
